1 answer

The Hg2+ ion forms complex ions with I- as follows: Hg2+ + I- HgI+ K1 =...

Question:

The Hg2+ ion forms complex ions with I- as follows:

Hg2+ + I-805e4be4-d312-4910-bca1-f50505cfc82b.jpg HgI+ K1 = 1.0 × 108
HgI+ + I-805e4be4-d312-4910-bca1-f50505cfc82b.jpg HgI2 K2 = 1.0 × 105
HgI2 + I-805e4be4-d312-4910-bca1-f50505cfc82b.jpg HgI3- K3 = 1.0 × 109
HgI3- + I-805e4be4-d312-4910-bca1-f50505cfc82b.jpg HgI42-

K4 = 1.0 × 108

A solution is prepared by dissolving 0.053 mol Hg(NO3)2 and 5.00 mol NaI in enough water to make 1.0 L of solution.

Calculate the equilibrium concentration of [HgI42- ].

[HgI42- ] = M

Calculate the equilibrium concentration of [I-].

[I-] = M

Calculate the equilibrium concentration of [Hg2+].

[Hg2+] = M


Answers

[HgI42-] = 0.053 M

[I-] = 4.8 M

[Hg2+] = 1.0 x 10-30 M

Explanation

Overall equation : Hg2+ + 4 I-\rightleftharpoons HgI42-

Overall K = (K1) * (K2) * (K3) * (K4)

Overall K = (1.0 x 108) * (1.0 x 105) * (1.0 x 109) * (1.0 x 108)

Overall K = 1.0 x 1030

initial moles Hg2+ = 0.053 mol

initial moles I- = 5.00 mol

moles HgI42- formed = initial moles Hg2+

moles HgI42- formed = 0.053 mol

moles I- consumed = 4 * (initial moles Hg2+)

moles I- consumed = 4 * (0.053 mol)

moles I- consumed = 0.212 mol

moles I- remaining = (initial moles I-) - (moles I- consumed)

moles I- remaining = (5.00 mol) - (0.212 mol)

moles I- remaining = 4.788 mol

.

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