Answers
1) SiCl4 + 2H2O -------> SiO2 + 4HCl
Hf(SiCl4) = -640.1kJ/mol
Hf(H2O) = -258.8 kJ/mol
Hf(SiO2) = -910.9kJ/mol
Hf(HCl) = -92.3kJ/mol
Hrxn =
n
Hf(products) -
n
Hf(reactants)
n
Hf(products) = -910.9+ 4(-92.3) = -1280.1 kJ/mol
n
Hf(reactants) = -640.1+ 2(-285.8) = -1211.7 kJ/mol
Hrxn = -1280.1 - (-1211.7) = -68.4 kJ/mol
2) 2C2H2 + 5O2 -----------> 4CO2 + 2H2O H = -2601 kJ ------- MULTIPLY BY 2
C8H8 + 10O2 -----------> 8CO2 + 4H2O H = - 4393 kJ ------ REVERSE THE REACTION
2( 2C2H2 + 5O2 -----------> 4CO2 + 2H2O) H = 2(-2601) kJ
4C2H2 + 10O2 -----------> 8CO2 + 4H2O H = -5202 kJ ---- 1
8CO2 + 4H2O -----------> C8H8 + 10O2H = +4393 kJ ----- 2
Adding equation 1 and 2 gives the equation 3
4C2H2(g) ------> C8H8(l) --------------- 3 H = ? kJ
H =
Heq1 +
Heq2 = -5202+4393 = -809 kJ
3) 2HBr -----> H2 + Br2
Hf(H-H) = 436 kJ/mol
Hf(Br-Br) = 193 kJ/mol
Hf(H-Br) = 366 kJ/mol
Hrxn =
n
Hf(products) -
n
Hf(reactants)
n
Hf(products) = 436 + 193 = 629 kJ/mol
n
Hf(reactants) = 2(366) = 732 kJ/mol
Hrxn = 732 - 629 = +103 kJ/mol